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* Jeffrey Youngblood

March 26, 2007

New coating could nix smudges, fogging on windshields, eyeglasses

WEST LAFAYETTE, Ind. -
Jeffrey Youngblood
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Materials engineers have created a new type of coating that attracts water yet beads oils - traits that are usually mutually exclusive - promising potential applications such as "self-cleaning" eyeglasses and antifogging car windshields and ski goggles.

The material prevents fogging by not allowing water to form beads on surfaces, said Jeffrey Youngblood, an assistant professor of materials engineering at Purdue University.

The coating consists of a single-molecule-thick layer of a material called polyethylene glycol, and each molecule is tipped with a Teflonlike "functional group" made with fluorine. Water molecules pass through the Teflonlike layer, which acts as a barrier to the larger oil molecules. Then the water is attracted to the polyethylene glycol immediately adjacent to the glass surface.

"So, it repels the oil but not the water," said Youngblood, who is working with materials engineering doctoral student John A. Howarter. "This is important because oil normally sticks to surfaces that attract water, a property we call hydrophilic. However, we now have one that's hydrophilic but that oil doesn't like."

Findings were detailed in a talk presented on Sunday (March 25) during the American Chemical Society's 233rd National Meeting & Exposition, which takes place through Thursday (March 29) in Chicago.

The findings demonstrate how an oily substance called hexadecane beads up on the coating while water spreads out to cover the surface instead of forming beads. Moreover, when water is attracted to the underlying polyethylene glycol layer it gets between the hexadecane and the glass, dislodging the oily film.

"If you place a droplet of oil and a droplet of water right next to each other, the water will move underneath the oil and cause it to fall off of the surface," Youngblood said.

Self-cleaning and antifogging behavior has been demonstrated in experiments using glass surfaces coated with the material.

Eyeglasses and goggles used by skiers are two obvious potential applications, along with automotive windshields. The inside of a car's windshield fogs because condensing water beads up on oily films that form on glass surfaces.

"If glass is perfectly clean, it won't fog, but glass is never perfectly clean because it picks up junk from the air and other sources," Youngblood said. "You will notice, for example, that it's difficult to remove fingerprints from eyeglasses. That's because of oils that are deposited from your skin onto the glass surface. Our material resists that junk from getting on the surface to begin with."

Unlike other "stimuli-responsive" coatings, the new material does not need to be pretreated with a solvent to achieve the desired behavior.

"It works as soon as you apply a drop of water," Youngblood said.

Eyeglasses coated with such a material would automatically shed fingerprints and other oily films when rinsed with water, eliminating the need to clean the surface with a cloth or to use soap. Such a material might be used as a permanent coating on glass surfaces and also could be added to liquid window cleaners to prevent fogging.

Youngblood came up with the idea for antifogging goggles while skiing several years ago.

Goggles are currently coated with antifogging materials that prevent water from beading, but this material doesn't work well if smudged with oils, such as those left by fingerprints, he said.

"I accidentally got a fingerprint on this surface, and I started thinking, 'Would it be possible to design a material that would work as an antifogging coating yet also resisted finger grease?'"

When a fluid lands on a glass surface, it forms beads having a distinctive curvature determined by the "contact  angle" of the substance. The higher the contact angle, the more a material is likely to form beads. Lowering the contact angle enough prevents substances from beading.

"This material maximizes oil's contact angle while minimizing water's contact angle," Youngblood said.

A patent is pending, and it will likely be several years before any products based on the technology are commercialized.

"This summer we are going to try to develop a material to put in window cleaners," Youngblood said. "We have also had discussions with a few companies about this, but commercialization is at least a few years away."

Writer: Emil Venere, (765) 494-4709, venere@purdue.edu

Source: Jeffrey Youngblood, (765) 496-2294, jpyoungb@purdue.edu

Purdue News Service: (765) 494-2096; purduenews@purdue.edu

PHOTO CAPTION:
Jeffrey Youngblood, a Purdue assistant professor of materials engineering, works with equipment that enables researchers to measure the "contact angle" of a liquid as it beads up on a surface. The measurements are needed for research to develop a new type of coating that has promising potential applications such as "self-cleaning" eyeglasses and antifogging car windshields and ski goggles. The material prevents fogging by not allowing water to form beads on surfaces. (Purdue News Service photo/David Umberger)

A publication-quality photo is available at http://news.uns.purdue.edu/images/+2007/youngblood-coating.jpg


ABSTRACT

Hydrophilic and Oleophobic Stimuli-Responsive Surfaces

Jeffrey P. Youngblood, jpyoungb@purdue.edu, and John A. Howarter, jhowarte@purdue.edu. School of Materials Engineering, Purdue University, West Lafayette, IN 47907

Stimuli-responsive polymers and surfaces have great potential to create "tunable" properties and smart materials. We demonstrate solvent sensitive stimuli-responsive behavior using brushes of polyethylene glycol with perfluorinated end-groups. Reaction time was varied to create surfaces with a wide range of brush densities. Surfaces had water contact angles lower than hexadecane contact angles. This behavior was independent of history and needed no solvent pretreatment for switch wetting behavior. Brush density was characterized and results are presented within this context. Possible uses for these surfaces are presented.


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